| Substituent groups in aryl- and arylalkylphosphanes: effects on coordination chemistry and catalytic properties | ||
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This thesis is based on the following papers, which are referred to in the text by their Roman numerals:
[I] Suomalainen P, Reinius HK, Riihimäki H, Laitinen RH, Jääskeläinen S, Haukka M, Pursiainen JT, Pakkanen TA & Krause AOI (2001) Hydroformylation of 1-hexene and propene with in situ formed rhodium phosphine catalysts. J Mol Catal A: Chem 169: 67–78.
[II] Suomalainen P, Riihimäki H, Jääskeläinen S, Haukka M, Pursiainen JT & Pakkanen TA (2001) Structural and catalytic properties of alkyl-substituted phosphanes. Effect of ortho-modification on rhodium-catalyzed 1-hexene hydroformylation. Catal Lett 77: 125–130.
[III] Reinius HK, Suomalainen P, Riihimäki H, Karvinen E, Pursiainen JT & Krause AOI (2001) o-Alkyl-substituted triphenylphosphines: activity and regioselectivity in rhodium-catalysed propene hydroformylation. J Catal 199: 302–308.
[IV] Riihimäki H, Suomalainen P, Reinius HK, Suutari J, Jääskeläinen S, Krause AOI, Pakkanen TA & Pursiainen JT (2003) o-Alkyl-substituted aromatic phosphanes for hydroformylation studies: synthesis, spectroscopic characterization and ab initio investigations. J Mol Catal A: Chem 200: 69–79.
[V] Riihimäki H, Kangas T, Suomalainen P, Reinius HK, Jääskeläinen S, Haukka M, Krause AOI, Pakkanen TA & Pursiainen JT (2003) Synthesis of new o-alkyl-substituted arylalkylphosphanes: study of their molecular structure and influence on rhodium-catalyzed propene and 1-hexene hydroformylation. J Mol Catal A: Chem 200: 81–94.